These can include work schedules that rotate employees and trainings. Labels: Colleges & UniversitiesConstructionFood SafetyHospitality & Food ServiceInformational ArticlesLaboratory SafetyManufacturingMunicipalitiesOther/General IndustryRetail & Grocery, Each year, the Association of Workers’ Compensation Boards of Canada (AWCBC) reports on the number of fatal workplace injuries…, In the 1960s, more women than ever entered the American workforce, highlighting issues of gender equality and workplace sexual…, Safe Driving in Hazardous Weather The Federal Highway Administration estimates that more than 1.2 million weather-related accidents happen on…, SAFETYSKILLS 519 NW 23rd Street Suite 200 Oklahoma City, OK 73103 T. 405-463-6656 SUPPORT | CONTACT US. nws4�8߷q\���L�I�u���-n���Z�{"��� If other hazard controls are unable to reduce employee exposure to safe levels, they may be required to use PPE. Product: Ammonium Hydroxide Revision Date: 12/03/2012 4/7 Engineering Controls: Ensure adequate ventilation. Identification . h��W_o�6�G�c��EJ�`�/�4��e��FQc��dH2�~�nw���n�ހm0���w�8��%���n�k@]�#R/r���p�q9�0.�� �*!�� "4sዃ3�$�F_Q���� �.L@N�ۈ�,߿gqk;6��~��������!���''�f�A�/�9���4iB8����NQ\������uՒ͛j�4W�J���l��o��EV|nc�EQ6''6 u`.�_��DB���J"��,�t�:}��E�F�����tN?꼆g첬�:g�B`��;�p5�k�§l>��gP-�6�ٗ�y���%�ؕ�֮-H���q���ޜ��㪡���i�O�I�kx_6)�f4*�,����{�Ks:��,�zW���ɥ^��q?�1�S�$+{ݵ�}�ٴ�y���c�R5M�0l/���X�m��bt�J72����J��Hʇ�xdwYu��'YU7㕮 Į�v�C.t��I�?� �ؤ����U�$��&yAhHHI�T��0�JA�¸gC �����wv��-���GO w98C %PDF-1.5 %���� If exposed, employees may experience: All these symptoms should be treated promptly and should be evaluated by a medical professional as soon as possible. Student safety sheets 31 Sodium hydroxide also applies to Soda lime and Potassium hydroxide Substance Hazard Comment Sodium or potassium hydroxide Solid . Never store ammonium hydroxide at any solution with or near food or food-type products. Employers should use appropriate control measures for ammonium hydroxide, including enclosures that separate the employee from the process and ensuring the use of both local and general ventilation. The employee should not be forced to vomit and should receive immediate medical attention. �Q8�Ɖ���-�!�t�k�T��E�aA�%Q���,��j�� �%���&�>U��B�O'�h������R %%EOF Replacing ammonium hydroxide with a safer alternative provides the best employee protection. colorless liquid with a strong odor and bad taste, Four Steps to Conducting a Job Safety Analysis in the Canadian Workplace, Train over any hazardous chemicals that employees may be exposed to, Train employees to detect and respond to a, Provide training over exposure protection, including, Eye irritation, including redness and pain, Contact burns, including blisters and burns. Synonyms/Generic Names: Aqueous ammonia, Ammonia solution . If ammonium hydroxide enters the eyes, they should be flushed for at least 30 minutes. It decomposes on … endstream endobj startxref 1125 0 obj <>stream Student Safety Sheets are teaching materials. Avoid release to theenvironment. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 07/06/1998 Revision date: 11/21/2016 Supersedes: 12/29/2015 Version: 2.0 01/26/2018 EN (English US) Page 1 SECTION 1: Identification . Search results for 1336-21-6 at Sigma-Aldrich. Industrial ammonium hydroxide can be found in solutions of up to 30%. Employers should also cover the hierarchy of hazard controls, ensuring all employees are familiar with effective forms of protection and how to use them. contains about 5% sodium hydroxide, 1% potassium hydroxide, 0.2% silicon dioxide, 14 – 19% water and the remainder calcium hydroxide (it is used to absorb carbon dioxide). ... Ammonia Ammonium Hydroxide 1336-21-6 NH3 13.5 – 14.5 Trade Secret Statement: Not applicable. If the chemical cannot be replaced, employers may use engineering controls like ventilation systems to reduce exposure. Additional training, a fit test and a medical evaluation are also required if employees will be using a respirator. If ingestion does occur, the mouth should be rinsed out and the employee should drink one to two glasses of water if they are able to drink. Household ammonia is typically a 10% solution and is commonly used to clean glass without leaving streaks. NIOSH also set a short-term suggested TWA of 35 ppm. It is corrosive to copper and zinc and can cause serious damage to skin and eyes. �~0��>b��|т�JA|�*W� NTe`�df {���Vg`V� ©CLEAPSS 2019 Student safety sheets 37 Ammonium salts Substance Hazard Comment Ammonium chloride Solid and concentrated solution (if 1.8 M or more) HARMFUL. It is not effective as a disinfectant. 1� �. However, ammonium hydroxide is one exception. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls WARNING! Columbus, WI. 0 �&[�����ם�������Dae��-��m�1��Z��cey4���"^�N��� ����ʤ���,����C������v��v�>�� If not breathing, give artificial respiration. Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. W. ARNING: harmful if swallowed, causes serious eye irritation. Ammonium Hydroxide and Hazard Controls. ]�]۶ݬ��k�8���)/P -1052/R 4/StmF/StdCF/StrF/StdCF/U(`�xY`X���RN� )/V 4>> endobj 1097 0 obj <>/Metadata 27 0 R/Pages 1093 0 R/StructTreeRoot 43 0 R/Type/Catalog>> endobj 1098 0 obj <>/MediaBox[0 0 612 792]/Parent 1093 0 R/Resources<>/ProcSet[/PDF/Text/ImageC]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1099 0 obj <>stream When employees work with industrial chemicals, they often are not using products they will find at home. While rare, ingestion can occur if employees using the chemical don’t wash their hands before eating or drinking. If direct contact occurs with the skin, flush the area with plenty of clean running water for at least 15 minutes. Safety Data Sheet . First Aid Procedures: Inhalation: Move to fresh air. endstream endobj 2187 0 obj <>/Metadata 59 0 R/Outlines 74 0 R/PageLayout/OneColumn/Pages 2184 0 R/StructTreeRoot 189 0 R/Type/Catalog>> endobj 2188 0 obj <>/ExtGState<>/Font<>/XObject<>>>/Rotate 0/StructParents 0/Type/Page>> endobj 2189 0 obj <>stream Glass, plastic or rubber containers can be used, but they must be stoppered and only partially filled. While it typically has a strong scent, this should not be used as a determination of its presence. 1095 0 obj <> endobj `��*��K h��̀�)��m��0� d�P���"�0�?���4;�W2�i�y8�.�������뀵�$v�F�st�R[�������x�q��'��l.K|�#�?��͈ұ4�,�r���u)�#e!e&��%�N�T8���/���K�َ. Used in everything from household cleaners to industrial processes, it is toxic in all solutions. ]��V�#N�U����V\�+A�f��$C3��+ +�� f:aNa�%t���;�c�0�L7%�nj/"�8�!F��ڢ�h��n�t�r������S����o6����rj ��!�������a��́Hl���Y��a�?旜_�0�`H ����o���(Ӿ�"�5���q���So��Fa���8�])r������fDհ��Fh� 'd��{�&��c����ۣ��.n%�G��Ѓ����I�P���2����u2�G�T�SGz�L�9���\̆�/�Z��. Product Use: Industrial, Manufacturing or Laboratory use . Hazards Not Otherwise This product is harmful to aquatic life. Employers can also choose to set their own PELs if they fall below the OSHA requirements. Copyright © 2020 SafetySkills. In addition to setting a workplace PEL, employers are also required by OSHA to develop and maintain a written hazard communication (HAZCOM) program. The most effective hazard controls are elimination and substitution. ��I��w�럝�������zF ?�Ӝ���ř����"gAbe�]��^�:J9�j�xw������|����o��|:h"�n��OojP�f��'o6P�+�H/ v�?l�z�Q^�s�G�����vެ,���И՛E�=K����3@� Ammonium hydroxide should always be stored in well-ventilated areas. Providing proper ventilation and PPE, as well as making sure all employees know what to do should an emergency arise, helps protect all workers from the dangers of this common, but dangerous, chemical. endstream endobj startxref %%EOF Although employees may use ammonium hydroxide both at home and at work, employers must ensure they are aware of the unique dangers of the chemical. Compare Products: Select up to 4 products. Soda lime. MSDS MATERIAL SAFETY DATA SHEET CHEMTREC: 800-424-9300 (USA) ----- 703-527-3887(Outside USA and Canada) CANUTEC: 613-996-6666 … �Er��b`l R�̋%�\F� s�37 Ammonium Hydroxide, ACS Reagent . h�bbd``b`ׁ�, ��$�":@�`�^�d-@� V�k��DH4�Xv@�g��$j��, ��!���� � ��K If breathing is difficult, give oxygen. Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH −], it is actually impossible to isolate samples of NH 4 OH. Contacts are not recommended for working with ammonium hydroxide and other hazardous chemicals, but if the employee is wearing them, they should remove them immediately if possible. When working with ammonium hydroxide, PPE will generally include: For employees who are trained to clean spills or are working with high concentrations of ammonium hydroxide, additional PPE will likely be required. 2218 0 obj <>stream It should also never be stored in areas with sewers. Call 911 for immediate assistance if the employee requires artificial respiration.
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